地面浓度反推法计算石化企业无组织排放源强

对某石化企业储罐区和原油脱酸装置区的无组织排放非甲烷总烃进行监测，对监测数据进行Pearson相关分析，运用地面浓度反推法计算源强。实验结果表明：原油脱酸装置区各采样线浓度间的相关性好，反推出的源强较为准确，50，100，150 m采样线的反推源强非常接近，分别为21.68，21.60，19.76 t/a；而储罐区监测浓度的相关性不佳，该区域的非甲烷总烃无组织排放源可能不单一，不适用地面浓度反推法计算其源强。     

昆明市污水排水系统产甲烷规律的模拟实验研究

通过对昆明市餐饮和居民生活污水厌氧模拟实验研究,初步探讨生活污水中CH4的产生规律,实验结果表明,在自然条件下,餐饮和居民生活污水中产生的甲烷浓度最大值分别为1.63 mg/L和3.82 mg/L。并且将COD、硫酸盐、硫化物、TN的浓度变化与甲烷浓度变化进行Pearson简单相关性分析,结果表明,1/COD、COD/硫酸盐和1/TN与甲烷在置信度为0.01时极显著相关,硫化物与甲烷在置信度为0.05时不相关;COD、硫酸盐和TN浓度的变化对生活污水中甲烷的产生起关键性作用。对居民生活污水中甲烷产生规律进行温度和pH控制分析研究,实验结果表明,生活污水在25~30℃时,24 h内甲烷产生量最大值为8.6494 mg/L,明显大于其他温度段的甲烷产生量;在pH为7~8之间时,甲烷的产生量在24 h内达到的最大值为3.0477 mg/L,明显高于其他pH控制段的甲烷产生量。     

基于物元模型的煤自燃危险性分析

为探索判断煤自燃的危险性新方法,在煤低温氧化试验的基础上,基于可拓理论构建了煤自燃危险性熵权和经验权的物元综合分析模型。采用该方法对4个不同煤样低温氧化试验数据进行自燃危险性分析,得出各煤样自燃危险性的等级及差异程度,并提出相应的防范对策。结果表明:4号煤样比其他煤样更具自燃危险性,需要重点防范。该方法的预测结果与实际情况相吻合。     

安全投入各要素分配方向的研究

针对灰色关联分析法存在的分辨系数的选择主观性较大,用关联系数的平均值得到的关联度降低了评价准确性等缺点,提出用经济学中的偏相关分析和不变替代弹性(CES)生产函数分析方法,建立安全投入与事故函数分析模型。应用SPSS和EViews软件,找出安全投入和事故之间偏相关系数绝对值最大的要素和标准化回归系数绝对值最大的要素,作为优先投入方向,并按照系数绝对值大小进行排序,为以后企业进行安全投入提供理论参考,避免企业资源的浪费。这两种方法可操作性强,主观随意性小,得到的结果可信性高。     

河南省旅游—经济发展类型及其开发战略

以河南省18个地市旅游与经济统计数据为样本,运用典型相关模型探讨旅游与区域经济发展之间的关系。第一典型变量揭示旅游产业发展有利于区域经济发展与对外开放;第二典型变量显示旅游发展能够促进工业化、拉动消费与固定资产投资。依据典型方程得分,划分为旅游与经济发达地区、较发达地区、一般地区等三种类型,并提出旅游发展策略。     

Interactions between metals accumulated in the narrow-clawed crayfish Astacus leptodactylus (Eschscholtz, 1823) in Dikilitaş Lake,Turkey

The accumulations of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn in the exoskeleton, gills, hepatopancreas and abdominal muscles of crayfish Astacus leptodactylus (Eschscholtz, 1823) were determined. The strongest correlation observed was between Cr and Ni in the gills (r?=?0.904); moderate to strong correlations between Al, Cr, Fe, Ni and Cu were also observed in gill tissue. Disregarding the gills, the strongest correlation was found between Cu and Zn in the hepatopancreas (r?=?0.808); the correlation between these two metals might have been a result of metallothionein activity. The accumulation of Pb was found to correlate with that of Cd in the exoskeleton, Cd and Zn in the gills, Zn and Cu in the hepatopancreas and Cu in the abdominal muscle. None of these correlations were present in lakewater and sediment samples, suggesting that the crayfish metabolism may be responsible for the co-accumulation of metal–metal pairs. As all correlations in non-gill tissues are observed between divalent metals, a shared transporter such as divalent metal transporter 1 might be involved in the accumulation of these metals.     

Organic farmers in islands: Agricultural management and attitude towards the environment

SUMMARY

This study explores differences among organic farmers who live in islands and have isolated small-size operations. The relationships between farmers' characteristics and attitudes and farm management were interpreted by studying how they manage their land, their attitudes towards the environment and alternative farming systems, and their involvement in organic farming. The research was carried out using questionnaires addressed to organic farmers on the island of Thassos. Nonlinear canonical correlation was applied for data analysis. This information could contribute to adjustment of policy decisions for on-farm diversification. Agricultural policy makers should approach organic farmers in northern Thassos (productive irrigated olive orchards with gentle slopes) by enacting standards to reduce the cost of alternative plant protection methods and promoting their products in order to maintain and expand organic farming. They should also approach organic farmers in southern Thassos (less productive, dry cultivated olive orchards with steep slopes, overgrazed and often abandoned) by providing them with the necessary information and appropriate agricultural know-how to effectively manage their farms. Organic farmers with stable off-farm income are more aware of environmental values and consider that they risk less than others in order to gain the benefits of alternative farming systems. However, they should attend training programmes to achieve economic success to allow them to continue farming organically.     

化学沉淀法强化常规工艺应急去除水中的镉

在常规工艺基础上,通过投加氢氧化钠,实验进行了应急去除重金属镉的研究。实验结果表明,该方法能有效去除饮用水水源的镉,效果稳定,可进行应急处理。对pH、镉初始浓度和混凝剂投加量3个影响因素的灰色关联分析表明,3个因素对镉去除效果影响的大小排序为:滤后水pH>混凝剂投加量>镉初始浓度。在水源镉突发污染时,在原有常规水处理工艺基础上,通过控制滤后水pH可实现对重金属镉的去除,pH的控制值与水源水质有关。     

The structure of the fire fighting foam surfactant Forafac®1157 and its biological and photolytic transformation products

For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by ¹H, ¹³C and ¹⁹F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility.